Role of hydrogen bonds in molecular relaxation during electron transport processes in biological systems

Krasilnikov P.M.
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In molecular systems with hydrogen bonds the mechanism of proton relaxation can take place. It is caused by redistribution of protons between two steady positions in double walls potential along the line of the hydrogen bond. This redistribution occurs at change of parameters of the double walls potential of the hydrogen bond which is caused by change of an electronic state of molecular system. The relaxation process is carried out due to a tunnel transfer of protons along the line of bonds. It is shown, that relaxation process can define temperature dependence of power parameters (either of the free energy differences ΔG or of the reorganization energy λ) of charge recombination P+Q-A from RC of Rhodobacter sphaeroides.

Keywords: hydrogen bonds, electron transport, proton relaxation
Citation in English: Krasilnikov P.M. Role of hydrogen bonds in molecular relaxation during electron transport processes in biological systems // Computer Research and Modeling, 2009, vol. 1, no. 3, pp. 297-320
Citation in English: Krasilnikov P.M. Role of hydrogen bonds in molecular relaxation during electron transport processes in biological systems // Computer Research and Modeling, 2009, vol. 1, no. 3, pp. 297-320
DOI: 10.20537/2076-7633-2009-1-3-297-320
URL: http://crm-en.ics.org.ru/journal/article/1591/
Creative Commons License This work is licensed under a Creative Commons Attribution-NoDerivs 3.0 Unported License.
According to Crossref, this article is cited by:
  • P. M. Krasilnikov, D. V. Zlenko, Igor Nikolaevich Stadnichuk. Exciton interaction of the chromophores - a tool to fine-tune the mechanism of non-photochemical quenching of phycobilisome in cyanobacteria. // Computer Research and Modeling. — 2015. — V. 7, no. 1. — P. 125. DOI: 10.20537/2076-7633-2015-7-1-125-144
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