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Some relationships between thermodynamic characteristics and water vapor and carbon dioxide fluxes in a recently clear-cut area
Computer Research and Modeling, 2017, v. 9, no. 6, pp. 965-980Views (last year): 15. Citations: 1 (RSCI).The temporal variability of exergy of short-wave and long-wave radiation and its relationships with sensible heat, water vapor (H2O) and carbon dioxide (CO2) fluxes on a recently clear-cut area in a mixed coniferous and small-leaved forest in the Tver region is discussed. On the basis of the analysis of radiation and exergy efficiency coefficients suggested by Yu.M. Svirezhev it was shown that during the first eight months after clearcutting the forest ecosystem functions as a "heat engine" i.e. the processes of energy dissipation dominated over processes of biomass production. To validate the findings the statistical analysis of temporary variability of meteorological parameters, as well as, daily fluxes of sensible heat, H2O and CO2 was provided using the trigonometrical polynomials. The statistical models that are linearly depended on an exergy of short-wave and long-wave radiation were obtained for mean daily values of CO2 fluxes, gross primary production of regenerated vegetation and sensible heat fluxes. The analysis of these dependences is also confirmed the results obtained from processing the radiation and exergy efficiency coefficients. The splitting the time series into separate time intervals, e.g. “spring–summer” and “summer–autumn”, allowed revealing that the statistically significant relationships between atmospheric fluxes and exergy were amplified in summer months as the clear-cut area was overgrown by grassy and young woody vegetation. The analysis of linear relationships between time-series of latent heat fluxes and exergy showed their statistical insignificance. The linear relationships between latent heat fluxes and temperature were in turn statistically significant. The air temperature was a key factor improving the accuracy of the models, whereas effect of exergy was insignificant. The results indicated that at the time of active vegetation regeneration within the clear-cut area the seasonal variability of surface evaporation is mainly governed by temperature variation.
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Mathematical model of respiratory regulation during hypoxia and hypercapnia
Computer Research and Modeling, 2017, v. 9, no. 2, pp. 297-310Views (last year): 16.Transport of respiratory gases by respiratory and circulatory systems is one of the most important processes associated with living conditions of the human body. Significant and/or long-term deviations of oxygen and carbon dioxide concentrations from the normal values in blood can be a reason of significant pathological changes with irreversible consequences: lack of oxygen (hypoxia and ischemic events), the change in the acidbase balance of blood (acidosis or alkalosis), and others. In the context of a changing external environment and internal conditions of the body the action of its regulatory systems aimed at maintaining homeostasis. One of the major mechanisms for maintaining concentrations (partial pressures) of oxygen and carbon dioxide in the blood at a normal level is the regulation of minute ventilation, respiratory rate and depth of respiration, which is caused by the activity of the central and peripheral regulators.
In this paper we propose a mathematical model of the regulation of pulmonary ventilation parameter. The model is used to calculate the minute ventilation adaptation during hypoxia and hypercapnia. The model is developed using a single-component model of the lungs, and biochemical equilibrium conditions of oxygen and carbon dioxide in the blood and the alveolar lung volume. A comparison with laboratory data is performed during hypoxia and hypercapnia. Analysis of the results shows that the model reproduces the dynamics of minute ventilation during hypercapnia with sufficient accuracy. Another result is that more accurate model of regulation of minute ventilation during hypoxia should be developed. The factors preventing from satisfactory accuracy are analysed in the final section.
Respiratory function is one of the main limiting factors of the organism during intense physical activities. Thus, it is important characteristic of high performance sport and extreme physical activity conditions. Therefore, the results of this study have significant application value in the field of mathematical modeling in sport. The considered conditions of hypoxia and hypercapnia are partly reproduce training at high altitude and at hypoxia conditions. The purpose of these conditions is to increase the level of hemoglobin in the blood of highly qualified athletes. These conditions are the only admitted by sport committees.
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Investigation of the averaged model of coked catalyst oxidative regeneration
Computer Research and Modeling, 2021, v. 13, no. 1, pp. 149-161The article is devoted to the construction and investigation of an averaged mathematical model of an aluminum-cobalt-molybdenum hydrocracking catalyst oxidative regeneration. The oxidative regeneration is an effective means of restoring the activity of the catalyst when its granules are coating with coke scurf.
The mathematical model of this process is a nonlinear system of ordinary differential equations, which includes kinetic equations for reagents’ concentrations and equations for changes in the temperature of the catalyst granule and the reaction mixture as a result of isothermal reactions and heat transfer between the gas and the catalyst layer. Due to the heterogeneity of the oxidative regeneration process, some of the equations differ from the standard kinetic ones and are based on empirical data. The article discusses the scheme of chemical interaction in the regeneration process, which the material balance equations are compiled on the basis of. It reflects the direct interaction of coke and oxygen, taking into account the degree of coverage of the coke granule with carbon-hydrogen and carbon-oxygen complexes, the release of carbon monoxide and carbon dioxide during combustion, as well as the release of oxygen and hydrogen inside the catalyst granule. The change of the radius and, consequently, the surface area of coke pellets is taken into account. The adequacy of the developed averaged model is confirmed by an analysis of the dynamics of the concentrations of substances and temperature.
The article presents a numerical experiment for a mathematical model of oxidative regeneration of an aluminum-cobalt-molybdenum hydrocracking catalyst. The experiment was carried out using the Kutta–Merson method. This method belongs to the methods of the Runge–Kutta family, but is designed to solve stiff systems of ordinary differential equations. The results of a computational experiment are visualized.
The paper presents the dynamics of the concentrations of substances involved in the oxidative regeneration process. A conclusion on the adequacy of the constructed mathematical model is drawn on the basis of the correspondence of the obtained results to physicochemical laws. The heating of the catalyst granule and the release of carbon monoxide with a change in the radius of the granule for various degrees of initial coking are analyzed. There are a description of the results.
In conclusion, the main results and examples of problems which can be solved using the developed mathematical model are noted.
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Forecasting the global temperature increase for the XXI century by means of a simple statistical model
Computer Research and Modeling, 2016, v. 8, no. 2, pp. 379-390Views (last year): 1.A simple statistical model is developed for the dynamics of the mean global annual temperature. The model combines the logarithmic effect of carbon dioxide concentration increase and the input by climatic cycles. Model parameters are determined from data of instrumental observations for 1850–2010. The model confirms the presence of climatic cycles with the period of 10.5 and 68.8 years in the global temperature dynamics. The trajectories of the global temperature changes for the XXI century are obtained under the scenarios of carbon dioxide concentration changes from the 5th IPCC Assessment Report. The comparison revealed that the global temperature trajectories from the Report are 0.9–1.8 °C above those obtained in the model.
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Modelling of carbon dioxide net ecosystem exchange of hayfield on drained peat soil: land use scenario analysis
Computer Research and Modeling, 2020, v. 12, no. 6, pp. 1427-1449The data of episodic field measurements of carbon dioxide balance components (soil respiration — Rsoil, ecosystem respiration — Reco, net ecosystem exchange — NEE) of hayfields under use and abandoned one are interpreted by modelling. The field measurements were carried within five field campaigns in 2018 and 2019 on the drained part of the Dubna Peatland in Taldom District, Moscow Oblast, Russia. The territory is within humid continental climate zone. Peatland drainage was done out for milled peat extraction. After extraction was stopped, the residual peat deposit (1–1.5 m) was ploughed and grassed (Poa pratensis L.) for hay production. The current ground water level (GWL) varies from 0.3–0.5 m below the surface during wet and up to 1.0 m during dry periods. Daily dynamics of CO2 fluxes was measured using dynamic chamber method in 2018 (August) and 2019 (May, June, August) for abandoned ditch spacing only with sanitary mowing once in 5 years and the ditch spacing with annual mowing. NEE and Reco were measured on the sites with original vegetation, and Rsoil — after vegetation removal. To model a seasonal dynamics of NEE, the dependence of its components (Reco, Rsoil, and Gross ecosystematmosphere exchange of carbon dioxide — GEE) from soil and air temperature, GWL, photosynthetically active radiation, underground and aboveground plant biomass were used. The parametrization of the models has been carried out considering the stability of coefficients estimated by the bootstrap method. R2 (α = 0.05) between simulated and measured Reco was 0.44 (p < 0.0003) on abandoned and 0.59 (p < 0.04) on under use hayfield, and GEE was 0.57 (p < 0.0002) and 0.77 (p < 0.00001), respectively. Numerical experiments were carried out to assess the influence of different haymaking regime on NEE. It was found that NEE for the season (May 15 – September 30) did not differ much between the hayfield without mowing (4.5±1.0 tC·ha–1·season–1) and the abandoned one (6.2±1.4). Single mowing during the season leads to increase of NEE up to 6.5±0.9, and double mowing — up to 7.5±1.4 tC·ha–1·season–1. This means increase of carbon losses and CO2 emission into the atmosphere. Carbon loss on hayfield for both single and double mowing scenario was comparable with abandoned hayfield. The value of removed phytomass for single and double mowing was 0.8±0.1 tC·ha–1·season–1 and 1.4±0.1 (45% carbon content in dry phytomass) or 3.0 and 4.4 t·ha–1·season–1 of hay (17% moisture content). In comparison with the fallow, the removal of biomass of 0.8±0.1 at single and 1.4±0.1 tC·ha–1·season–1 double mowing is accompanied by an increase in carbon loss due to CO2 emissions, i.e., the growth of NEE by 0.3±0.1 and 1.3±0.6 tC·ha–1·season–1, respectively. This corresponds to the growth of NEE for each ton of withdrawn phytomass per hectare of 0.4±0.2 tС·ha–1·season–1 at single mowing, and 0.9±0.7 tС·ha–1·season–1 at double mowing. Therefore, single mowing is more justified in terms of carbon loss than double mowing. Extensive mowing does not increase CO2 emissions into the atmosphere and allows, in addition, to “replace” part of the carbon loss by agricultural production.
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